Advanced Potentiometry Potentiometric Titrations and Their Systematic Errors

This monograph features the calculation of the total potential anomalies/systematic errors in emf cells containing either mixtures of strong electrolytes or equilibrium systems at all the experimental conditions generally used in potetiometric titrations. A critical analysis of these methods is presented. At present, there are serious systematic errors in the calculation methods used at the interpretation of emf data, which result in erroneous suggestion of the complexes formed (often polynuclear which do not exist!).

Why is this book needed?
Potentiometry is a classical investigation method. It is important that this method is correct, free from systematic errors and it that it describes both nature and the enviroment correctly.